Adsorption of phenol over bio-based silica/calcium carbonate (CS-SiO2/CaCO3) nanocomposite synthesized from waste eggshells and rice husks

View article
1487 days ago
A great article I helped peer review published today in @PeerJPhysChem https://t.co/OlVRZTrKyR #NanomaterialsandNanochemistry #KineticsandReactions
PeerJ Physical Chemistry

Main article text

 

Introduction

Materials and Methods

Chemical and reagents

Preparation and synthesis of the adsorbents

Instrumental analysis

Adsorption experiment

where K1 (mg/g min) is the rate constant, qe (mg/g) is the adsorption capacity at equilibrium, and qt (mg/g) is the adsorption capacity at time t. The slope of the Log (qe − qt) vs t was used for the determination of the equilibrium rate constant K1. The Pseudo-second order kinetic was determined using Eq. (2): tqt=1K2qe2+1qtt
The rate constant (K2) and qe are calculated from the intercept and slope of the plot of t/qt vs t (Husein, Hassanien & Al-Hakkani, 2019). The percentage removal efficiency of phenol and the amount adsorbed over the adsorbent were determined using Eq. (3): R%=[CiCeCi]x100
where Ci and Ce are the initial and the equilibrium concentrations of phenol in mg/L. The uptake capacity (mg/g) of the sorbent for each concentration of phenol at equilibrium were determined using Eq. (4): qe(mg/g)=[CiCe)/M]xV
where V is the volume of the solution in L, while M is the mass of the biosorbent (g). The adsorption behavior was analyzed using The Langmuir (Langmuir, 1916) and Freundlich (Freundlich, 1906) isotherms models. The following relation represents the linear form of the Langmuir isotherm model: Ceqe=1qmKe+Ceqm
where qe is the amount adsorbed at equilibrium (mg/g), Ce is the equilibrium concentration of the adsorbate (mg/L), and qm (mg/g) and Ke (L/mg) are the Langmuir constants related to the maximum adsorption capacity and the energy of adsorption, respectively. These constants are evaluated from the intercept and slope of the linear plot experimental data of Ce/qe (g/mg) vs Ce (L/mg). The following relation gives the linear form of the Freundlich isotherm model: Logqe=LogKf+InLogCe
where Kf and 1/n are the Freundlich constants related to adsorption capacity and adsorption intensity of the adsorbent. The values of Kf and 1/n were derived from the intercept and slope of the linear plot of Logqe vs LogCe. The dimensionless constant (separation factor, RL) taking from the Langmuir isotherm was estimated using Eq. (7): RL=1[KLCi+1]
where Ci is the initial concentration and KL the concentration of Langmuir. If RL = 0, the adsorption is irreversible, is favorable when 0 < RL < 1, linear when RL = 1 and unfavorable when RL >1 (Chraibi et al., 2016).

Results and Discussion

Characterization of adsorbent

FTIR analysis

XRD analysis

FESEM/EDX analysis

Factors affecting adsorption behaviors

Kinetic adsorption study

Adsorption isotherms study

Adsorption and removal mechanism of phenol over CS–SiO2/CaCO3 nanocomposite

Conclusion

Supplemental Information

Raw adsorption data.

DOI: 10.7717/peerj-pchem.17/supp-1

FESEM and EDX raw data for RHSiO2.

DOI: 10.7717/peerj-pchem.17/supp-2

FESEM and EDX raw data for CS-SiO2.CaCO3.

DOI: 10.7717/peerj-pchem.17/supp-4

FESEM and EDX raw data for ESCaCO3.

DOI: 10.7717/peerj-pchem.17/supp-6

Additional Information and Declarations

Competing Interests

The authors declare that they have no competing interests.

Author Contributions

Ibrahim Birma Bwatanglang conceived and designed the experiments, performed the experiments, analyzed the data, performed the computation work, prepared figures and/or tables, authored or reviewed drafts of the paper, and approved the final draft.

Samuel T. Magili analyzed the data, authored or reviewed drafts of the paper, and approved the final draft.

Iliya Kaigamma conceived and designed the experiments, performed the experiments, analyzed the data, prepared figures and/or tables, and approved the final draft.

Data Availability

The following information was supplied regarding data availability:

Raw data are available in the Supplemental Files.

Funding

This research is supported by the Institutional Based Research (IBR) funded by Research Tertiary Education Trust Fund, Nigeria (TETFUND). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.

13 Citations 3,119 Views 1,416 Downloads

Your institution may have Open Access funds available for qualifying authors. See if you qualify

Publish for free

Comment on Articles or Preprints and we'll waive your author fee
Learn more

Five new journals in Chemistry

Free to publish • Peer-reviewed • From PeerJ
Find out more